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Defense Intelligence Reference Document Metallic Glasses For Aerospace Applications

Defense Intelligence Agency · 30 pages · text from the file's own layer

The Defense Intelligence Agency issued this Defense Intelligence Reference Document (DIA-08-0911-012), dated 14 December 2009, as one of its FY 2009 advanced technology reports under the Advanced Aerospace Weapon System Applications (AAWSA) Program. It reviews how metallic glasses are structured and processed, their mechanical properties, and metallic glass matrix composites. It concludes that dendritic composites could replace high-strength steels in some aerospace parts. It adds that wide aerospace use depends critically on developing new lightweight glass-forming alloys.

  • p. 1 …Defense Intelligence Reference Document Acquisition Threat Support Metallic Glasses: Status and Prospects for Aerospace Applications UNCLASSIFIED…
  • p. 2 UNCLASSIFIEDh'FOA OFFili6ilil1k WEE o•lb>f Metallic Glasses: Status and Prospects for Aerospace Applications Prepared…
  • p. 3 …12 Metallic Glass Matrix Composites ......................................................................... 13 Processing and Structure of Composites ..... ~ .................................................... 13 Ex Situ Composites ............................................................................................ 14…
  • p. 4 …Examples of Processing of Metallic Glasses ........................................................ 4 4. Shear Bands ....................................................................................................... 8 5. Fatigue Limit of Metallic…
  • p. 5 UNCLASSIFIED/.'FOR Qffili&l.t.k Uli& e•lk>J Metallic Glasses: Status and Prospects for…
  • p. 6 …in all these areas, and that metallic glasses and metallic glass matrix composites will see increasing…
  • p. 7 UNCLASSIFIED,'} I Clll err1e1111t YSI 8Pllsit.f Metallic Glasses STRUCTURE The atomic-scale structure of most…
  • p. 8 …Metallic crystals nucleate and grow quickly, making production of a metallic glass more challenging. 2 UNCLASSIFIED…
  • p. 9 UNCLASSIFIED//F8R IFFH!JIAL U91!! 8Ht¥ One way to quantify the ability of a metallic alloy…
  • p. 10 …GFFl61ilill WSE eP•tY Casting and Molding Like other alloys, metallic glasses can be cast into…
  • p. 11 …The use of fasteners and adhesives is much the same for metallic glasses as for any…
  • p. 12 …In this section, we review the mechanical behavior of metallic glasses, with particular attention to properties…
  • p. 13 …In any loading geometry where the metallic glass experiences significant tensile loading, fracture occurs on a…
  • p. 14 …Produced by bending of a zirconium-based metallic glass. 14 Fracture Toughness Fracture toughness is a…
  • p. 15 UNCLASSIFIED,} FOR OFFICIAL tl91! 9HI!'{ Even some metallic glasses with reasonable toughness may be embrittled by…
  • p. 16 …Fatigue Limit of Metallic Glasses and Metallic-Glass-Matrix Composites. Fatigue life data for single-phase…
  • p. 17 …Deformation Map for Metallic Glasses. As a function of temperature (normalized to the glass transltlon temperature…
  • p. 18 …Magnetic, Electrical, Optical, Thermal, and Acoustic Although most of the current interest in metallic glasses centers…
  • p. 19 …Wedge of a zirconium-based bulk metallic glass produced by casting. Note the sntny metallic luster…
  • p. 20 …One of the most promising recent advances in the metallic glass field is the development of…
  • p. 21 …The size of the plastic zone varies from ~ 1 μm for "intrinsically brittle" metallic glasses to…
  • p. 22 …For instance, monolithic titanium-based metallic glasses (like all metallic glasses) have essentially zero tensile ductility…
  • p. 23 …Figure 9 illustrates the mechanical properties of metallic glasses and metallic glass matrh< composites compared with…
  • p. 24 …bath normalized to density) of metallic glasses (yellow) and dendrltic metallic glass matrix composites (red) compared…
  • p. 25 …A final possibility is that metallic glasses might be combined with polymer composites into metal-fiber…
  • p. 26 …Attempts to make aluminum-based metallic glass components by consolidating amorphous powders have met with limited…
  • p. 27 …This ease of processing could offset the higher raw materials costs for metallic glasses, making them…
  • p. 28 …Summary and Recommendations Metallic glasses combine some of the advantageous mechanical properties of metals- strength, stiffness…
  • p. 29 …Liu, Chapter 4 in Bulk Metallic Glasses, .M. Miller and P. K. Liaw, eds. (Springer, 2009…
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Metallic glass foams (see above) also provide Intriguing possibilities for structural
applications. It has recently been-shown that metallic glass foams with outstanding
strength can be formed by controlling the size of the ligaments between pores. 40 This is
a new development, and these foams have not been fully characterized, but it seems
likely that optimized foams will have a specific stiffness (E/p) superior to that of
polymer foams, along with high strength and acoustic damping. Such structural foams
could be useful in applications requiring strength and stiffness under compressive loads,
such as structural panels for extraterrestrial buildings. Conceivably, such structural
foams might even be produced an site (from raw feedstock), reducing the volume of
material that needs to be launched.
A final possibility is that metallic glasses might be combined with polymer composites
into metal-fiber laminate materials. Similar laminates (with crystalline aluminum alloys)
are being employed in large quantities on the new Airbus 380 and are likely to find
increased application in the future. 41 The use of metallic glasses in these laminates is
appealing because of their high specific strength (although the specific stiffness is lower
than that of aluminum). Furthermore, the individual layers in the laminate are
sufficiently thin that a wide range of glass-forming alloys might be considered (in
contrast to thicker structural sections, which will be limited by the glass-forming ability
of the alloy).
OTHER APPLICATIONS
Monolithic metallic glasses are unique among metallic materials in having no
microstructure at length scales of more than a few atomic spacings. In principle then,
metallic glasses should be capable of replicating features down .to this scale. This
possibility is facilitated by the ability of metallic glasses to be formed in the supercooled
liquid temperature range with controllable viscosity. Indeed, superplastic forming of
metallic glass surfaces with features as small as 13 nanometers has been
demonstrated.42 This ability could be exploited for direct embossing of nanostructures
in polymers or other materials. Structures on this length scale are also potentially
useful as diffraction gratings for ultraviolet and soft x-ray radiation.
In a related area, metallic glasses have a variety of useful properties for application in
micro-electromechanical system (MEMS} actuators, including large elastic strains and
high resilience (elastic strain energy storage), good corrosion and wear resistance, and
an excellent surface finish. 43 The scale of these devices is smaller than the plastic zone
size (Equation 1 above), making brittle fracture.unlikely. Furthermore, a much wider
variety of amorphous alloys can be made In thin film form (by vapor deposition) than is
possible by casting.
Finally, the magnetic properties of certain amorphous alloys have long been exploited.
For instance, their low coercivity and high electrical resistivity make ferromagnetic
amorphous alloys attractive as high-efficiency electrical transformers, particularly at
high frequencies. Such applications are likely to continue well into the future.
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Report, from the dia collection. The PDF is mirrored here; the original link is under it. 30 pages are in the text index: search them above, or from the library's search.