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Defense Intelligence Reference Document Metallic Glasses For Aerospace Applications

Defense Intelligence Agency · 30 pages · text from the file's own layer

The Defense Intelligence Agency issued this Defense Intelligence Reference Document (DIA-08-0911-012), dated 14 December 2009, as one of its FY 2009 advanced technology reports under the Advanced Aerospace Weapon System Applications (AAWSA) Program. It reviews how metallic glasses are structured and processed, their mechanical properties, and metallic glass matrix composites. It concludes that dendritic composites could replace high-strength steels in some aerospace parts. It adds that wide aerospace use depends critically on developing new lightweight glass-forming alloys.

  • p. 1 …Defense Intelligence Reference Document Acquisition Threat Support Metallic Glasses: Status and Prospects for Aerospace Applications UNCLASSIFIED…
  • p. 2 UNCLASSIFIEDh'FOA OFFili6ilil1k WEE o•lb>f Metallic Glasses: Status and Prospects for Aerospace Applications Prepared…
  • p. 3 …12 Metallic Glass Matrix Composites ......................................................................... 13 Processing and Structure of Composites ..... ~ .................................................... 13 Ex Situ Composites ............................................................................................ 14…
  • p. 4 …Examples of Processing of Metallic Glasses ........................................................ 4 4. Shear Bands ....................................................................................................... 8 5. Fatigue Limit of Metallic…
  • p. 5 UNCLASSIFIED/.'FOR Qffili&l.t.k Uli& e•lk>J Metallic Glasses: Status and Prospects for…
  • p. 6 …in all these areas, and that metallic glasses and metallic glass matrix composites will see increasing…
  • p. 7 UNCLASSIFIED,'} I Clll err1e1111t YSI 8Pllsit.f Metallic Glasses STRUCTURE The atomic-scale structure of most…
  • p. 8 …Metallic crystals nucleate and grow quickly, making production of a metallic glass more challenging. 2 UNCLASSIFIED…
  • p. 9 UNCLASSIFIED//F8R IFFH!JIAL U91!! 8Ht¥ One way to quantify the ability of a metallic alloy…
  • p. 10 …GFFl61ilill WSE eP•tY Casting and Molding Like other alloys, metallic glasses can be cast into…
  • p. 11 …The use of fasteners and adhesives is much the same for metallic glasses as for any…
  • p. 12 …In this section, we review the mechanical behavior of metallic glasses, with particular attention to properties…
  • p. 13 …In any loading geometry where the metallic glass experiences significant tensile loading, fracture occurs on a…
  • p. 14 …Produced by bending of a zirconium-based metallic glass. 14 Fracture Toughness Fracture toughness is a…
  • p. 15 UNCLASSIFIED,} FOR OFFICIAL tl91! 9HI!'{ Even some metallic glasses with reasonable toughness may be embrittled by…
  • p. 16 …Fatigue Limit of Metallic Glasses and Metallic-Glass-Matrix Composites. Fatigue life data for single-phase…
  • p. 17 …Deformation Map for Metallic Glasses. As a function of temperature (normalized to the glass transltlon temperature…
  • p. 18 …Magnetic, Electrical, Optical, Thermal, and Acoustic Although most of the current interest in metallic glasses centers…
  • p. 19 …Wedge of a zirconium-based bulk metallic glass produced by casting. Note the sntny metallic luster…
  • p. 20 …One of the most promising recent advances in the metallic glass field is the development of…
  • p. 21 …The size of the plastic zone varies from ~ 1 μm for "intrinsically brittle" metallic glasses to…
  • p. 22 …For instance, monolithic titanium-based metallic glasses (like all metallic glasses) have essentially zero tensile ductility…
  • p. 23 …Figure 9 illustrates the mechanical properties of metallic glasses and metallic glass matrh< composites compared with…
  • p. 24 …bath normalized to density) of metallic glasses (yellow) and dendrltic metallic glass matrix composites (red) compared…
  • p. 25 …A final possibility is that metallic glasses might be combined with polymer composites into metal-fiber…
  • p. 26 …Attempts to make aluminum-based metallic glass components by consolidating amorphous powders have met with limited…
  • p. 27 …This ease of processing could offset the higher raw materials costs for metallic glasses, making them…
  • p. 28 …Summary and Recommendations Metallic glasses combine some of the advantageous mechanical properties of metals- strength, stiffness…
  • p. 29 …Liu, Chapter 4 in Bulk Metallic Glasses, .M. Miller and P. K. Liaw, eds. (Springer, 2009…
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deformation can proceed in a stable manner by generation and subsequent arrest of
shear bands. The key to composite design is to produce a microstructure with the
correct length scale to prevent propagating shear bands from becoming catastrophic
cracks. This turns out to be relatively difficult with ex situ composites, for reasons of
processing described above. As a result, the recently developed dendritic in situ
composites have the most promising properties, and we focus the remainder of our
discussion on them.
STRENGTH AND DUCTILITY: PLASTIC DEFORMATION
As with other composite materials, the yield strength of metallic glass matrix
composites can be approximated as a simple rule of mixtures based on the volume
fraction of the two phases. Because the ductile crystalline phases useful for limiting
shear band propagation are weaker than the amorphous matrix, in producing a
composite, some sacrifice in strength is inevitable. However, the gains in tensile
ductility can be significant. For instance, monolithic titanium-based metallic glasses
(like all metallic glasses) have essentially zero tensile ductility, but in situ composites
based on titanium have been reported with tensile elongation as large as 12 percent. 35
This is comparable to the ductility of Ti-6Al-4V (the most common conventional
titanium alloy), but in a material with about 30 percent greater strength. The properties
of metallic glass matrix composites and more conventional materials are further
compared below.
FRACTURE AND FATIGUE
The development of a stable plastic zone means additional energy is required for crack
propagation, making in situ composites much more resistant to fracture and fatigue
than are single-phase glasses. For instance, the plane-strain fracture toughness of
some zirconium-based in situ composites can exceed 170 MPa m 112-7 times greater
than that of single-phase glasses and greater than that of virtually any other metallic
alloy.36 This resistance to crack propagation is also manifested as improved fatigue
performance. The fatigue strength of the zirconium-based in situ composites is 20-30
percent of the tensile strength; in comparison, monolithic metallic glasses have a
fatigue strength of only ~ 5 percent of the tensile strength. 37 The fatigue strength of
the in situ composltes is thus comparable to that of conventional structural alloys.
Aerospace Applications of Metallic Glasses
STRUCTURAL APPLICATIONS
The key properties of materials for structural applications in aerospace are:
• Strength.
• Stiffness (Young's modulus).
• Density (weight).
• Fracture toughness (damage tolerance).
16
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Report, from the dia collection. The PDF is mirrored here; the original link is under it. 30 pages are in the text index: search them above, or from the library's search.