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Defense Intelligence Reference Document Metallic Glasses For Aerospace Applications

Defense Intelligence Agency · 30 pages · text from the file's own layer

The Defense Intelligence Agency issued this Defense Intelligence Reference Document (DIA-08-0911-012), dated 14 December 2009, as one of its FY 2009 advanced technology reports under the Advanced Aerospace Weapon System Applications (AAWSA) Program. It reviews how metallic glasses are structured and processed, their mechanical properties, and metallic glass matrix composites. It concludes that dendritic composites could replace high-strength steels in some aerospace parts. It adds that wide aerospace use depends critically on developing new lightweight glass-forming alloys.

  • p. 1 …Defense Intelligence Reference Document Acquisition Threat Support Metallic Glasses: Status and Prospects for Aerospace Applications UNCLASSIFIED…
  • p. 2 UNCLASSIFIEDh'FOA OFFili6ilil1k WEE o•lb>f Metallic Glasses: Status and Prospects for Aerospace Applications Prepared…
  • p. 3 …12 Metallic Glass Matrix Composites ......................................................................... 13 Processing and Structure of Composites ..... ~ .................................................... 13 Ex Situ Composites ............................................................................................ 14…
  • p. 4 …Examples of Processing of Metallic Glasses ........................................................ 4 4. Shear Bands ....................................................................................................... 8 5. Fatigue Limit of Metallic…
  • p. 5 UNCLASSIFIED/.'FOR Qffili&l.t.k Uli& e•lk>J Metallic Glasses: Status and Prospects for…
  • p. 6 …in all these areas, and that metallic glasses and metallic glass matrix composites will see increasing…
  • p. 7 UNCLASSIFIED,'} I Clll err1e1111t YSI 8Pllsit.f Metallic Glasses STRUCTURE The atomic-scale structure of most…
  • p. 8 …Metallic crystals nucleate and grow quickly, making production of a metallic glass more challenging. 2 UNCLASSIFIED…
  • p. 9 UNCLASSIFIED//F8R IFFH!JIAL U91!! 8Ht¥ One way to quantify the ability of a metallic alloy…
  • p. 10 …GFFl61ilill WSE eP•tY Casting and Molding Like other alloys, metallic glasses can be cast into…
  • p. 11 …The use of fasteners and adhesives is much the same for metallic glasses as for any…
  • p. 12 …In this section, we review the mechanical behavior of metallic glasses, with particular attention to properties…
  • p. 13 …In any loading geometry where the metallic glass experiences significant tensile loading, fracture occurs on a…
  • p. 14 …Produced by bending of a zirconium-based metallic glass. 14 Fracture Toughness Fracture toughness is a…
  • p. 15 UNCLASSIFIED,} FOR OFFICIAL tl91! 9HI!'{ Even some metallic glasses with reasonable toughness may be embrittled by…
  • p. 16 …Fatigue Limit of Metallic Glasses and Metallic-Glass-Matrix Composites. Fatigue life data for single-phase…
  • p. 17 …Deformation Map for Metallic Glasses. As a function of temperature (normalized to the glass transltlon temperature…
  • p. 18 …Magnetic, Electrical, Optical, Thermal, and Acoustic Although most of the current interest in metallic glasses centers…
  • p. 19 …Wedge of a zirconium-based bulk metallic glass produced by casting. Note the sntny metallic luster…
  • p. 20 …One of the most promising recent advances in the metallic glass field is the development of…
  • p. 21 …The size of the plastic zone varies from ~ 1 μm for "intrinsically brittle" metallic glasses to…
  • p. 22 …For instance, monolithic titanium-based metallic glasses (like all metallic glasses) have essentially zero tensile ductility…
  • p. 23 …Figure 9 illustrates the mechanical properties of metallic glasses and metallic glass matrh< composites compared with…
  • p. 24 …bath normalized to density) of metallic glasses (yellow) and dendrltic metallic glass matrix composites (red) compared…
  • p. 25 …A final possibility is that metallic glasses might be combined with polymer composites into metal-fiber…
  • p. 26 …Attempts to make aluminum-based metallic glass components by consolidating amorphous powders have met with limited…
  • p. 27 …This ease of processing could offset the higher raw materials costs for metallic glasses, making them…
  • p. 28 …Summary and Recommendations Metallic glasses combine some of the advantageous mechanical properties of metals- strength, stiffness…
  • p. 29 …Liu, Chapter 4 in Bulk Metallic Glasses, .M. Miller and P. K. Liaw, eds. (Springer, 2009…
UNCLASSIFIEDf,SP811: 8FFllll1k WOE SHIia¥
Table 2. Comparison of strengths of Amorphous and Crystalline
Aluminum Alloys. Compared with tne theoretical maximum strength
(taken to be μ/30, whereμ is the,shear modulus of pure aluminum).
Theoretical
Strength (Defect-
Free Crystal)
Typical High-
~treligth
Aluminum Alloy
(7xxx Series)11
Best Crystalline
Aluminum Alloy12
Aluminum-Based '
•• Meta me Glass13
Yieid Stress (MPa)
400-500
770
1,280
0/o of Theoretical
strength
25-31%
48%
80%
Unfortunately, the lack of dislocations in amorphous alloys.is also theirAcl::lilles' heel. In
crystalline alloys, dislocations move a.nd multiply in response to applied stresses,
resulting in dislocation tangles that increase the resistc:1nce to further dislotatio11
motion. This process, called'strain hardening, is of crucial importance because'",t makes
plastic deformation stable. If one region of a crystalline materiaf yields and begins to
plastically deform, the deforming region strain hardens, and so another region will
deform instead. The result is that the plastic deformation is not concentrated but rather
spreads through a large volume of material. Metallic glasses, lacking dislocations, do
not strain harden and in fact strain soften in response to plastic deformation. This
means that as soon as any one region yields, any further deformation will occur in the
same region. This process, known as shear localization, leads to the formation of shear
bands {Figure 4). In any loading geometry where the metallic glass experiences
significant tensile loading, fracture occurs on a single dominant shear band with
essentially zero tensile ductility.2 Metallic glasses therefore fracture in an abrupt,
apparently brittle manner on the macroscopic scale (even though there can be
significant plasticity on a microscopic scale). This lack of ductility is of obvious concern
to designers interested in structural applications. Furthermore, it limits the ability to
fabricate metallic glasses into different shapes by deformation processing (by rolling or
forging, for instance) after casting.
2 This assumes there Is no geometrical constraint preventing fracture. Some geometries (such as simple bending)
can involve tensile loading, but there can still be significant plastic deformation because the geometrical constraints
inhibit propagating of shear bands across the specimen.
7
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